How To Change Blog Container Margin/Padding?
In Wordpress Admin Panel go to Appearance > Editor section
After opening Editor Section, click Toggle Navigation which in on left top corner of Editor Section Screen.
Now Click on Templates and Open Archive
After Archive is opened, select List Views.
In List Views, open the heirarchy of group Select Column. Make sure that your Main Blog column is selected in Block Editor.
Now select Block Settings in Right Top Corner, under Dimensions change Padding and Margin. If either of Padding or Margin is missing from the Dimensions panel, click on the three dots to enable it.
Once you change the padding or margin, you should see the effect right away in the Block Editor.